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The Look of Love...

Say what you like about chemistry - you can't bottle it.

Brad Pitt and Anjelina Jolie

We're all looking for Mr or Ms Right (if only for a night). And the movies is traditionally a good place to start: quality time in the dark, just you and your date, Brad Pitt and Angelina Jolie. We like to imagine that great on-screen chemistry will rub off on us, somehow. And sometimes maybe it does.

But what makes a great on-screen couple? Two or three years ago the Royal Society of Chemistry conducted a study. According to the organization's spokesman, Dr John Emsley, 'Like anything to do with chemistry, it is all about mixing up a cocktail of ingredients to get the right result.'

And you thought science was hard! The RSC came up with a top ten list topped by Katharine Hepburn and Spencer Tracy, naturally, but spoiled it all by putting Elizabeth Taylor and Richard Burton in the number two spot, which makes you wonder what these eggheads were thinking.

Taylor and Burton may have been great together off-screen (their tempestuous Romance included two divorces) but on screen the only time they showed serious rapport was when they battled it out in Who's Afraid of Virginia Woolf. Taylor had more going on with (gay) Montgomery Clift in A Place in the Sun, James Dean in Giant, or indeed with Lassie.

Despite the pre-eminent example of Bogie and Bacall - who visibly fell in love during the filming of To Have and Have Not - it's not unusual for real-life couples to look wrong together on screen: think of Sean Penn and Madonna, Tom Cruise and Nicole Kidman, Antonio Banderas and Melanie Griffith. Nobody watching Bull Durham would pair off Susan Sarandon with Tim Robbins, and Tom Hanks always worked better with Meg Ryan than his real-life wife, actress Rita Wilson.

Out of Sight: Jennifer Lopez and George Clooney

Conversely, some of the most famous on-screen couples didn't get on too well: Fred Astaire famously ruffled Ginger Rogers' feathers; Debra Winger had a rotten time making An Officer And A Gentleman, but she still sizzled with Richard Gere; and the reported antagonism between Jennifer Lopez and George Clooney on the set of Out of Sight generated plenty of heat - in fact that may be the last time la Lopez showed chemistry with anyone.

J-Lo is at her best when she's allowed to be strong, pitted against a strong co-star. Opposites don't always attract, but they do have the built-in tension to sustain a story. Making nice with Matthew McConaughey, Ralph Fiennes or Richard Gere is no fun for Lopez or us. Certainly Ben Affleck didn't do it for her.

The fact that female roles today are rarely developed enough to hold up their end may account for how few couples in modern cinema compete with memories of, say, Myrna Loy and William Powell in The Thin Man, or Cary Grant and Eva Marie Saint in North by Northwest, or even John Wayne and Maureen O'Hara in The Quiet Man.

Of course it also doesn't help that most movie stars seem to have given up even the pretence of monogamy. Back in the day, Hepburn and Tracy made nine films together. Rogers and Astaire went one better, with ten. Myrna Loy and William Powell teamed 14 times. These days the closest we get would be Owen Wilson and Ben Stiller (8 times).

Still, do not despair. Romance isn't quite dead yet, as these modern lovers prove:

Kate Winslet and Leonardo DiCaprio: Titanic

Okay, it's an obvious place to start, but you have to admit it would be great to see them back together on screen now they're all grown up.

Uma Thurman and John Travolta: Pulp Fiction

They can't help it. It's the way they compliment each other in the dance floor. Granted, Be Cool put a big chill on this romance.

Viggo Mortensen and Maria Bello: A History of Violence

Ra-ra-ra! Married couples can still have fun (even if one of them does lead a double life for extra spice).

Julie Delpy and Ethan Hawke: Before Sunrise/Before Sunset

Because the mind is the sexiest organ in the human body: these two are so made for each other, even Uma Thurman doesn't stand a chance.

Halle Berry and Billy Bob Thornton: Monster's Ball

This couple shouldn't click, but they do. She gives him sex appeal. He gives her passion. Neither has found a better on-screen mate.

Adam Sandler and Drew Barrymore: The Wedding Singer/50 First Dates

It can't be easy to bring out the romantic in perpetual adolescent Adam Sandler, but Barrymore's infectious joie de vivre works wonders.

Jake Gyllenhaal and Heath Ledger: Brokeback Mountain

The most moving love story in recent years. It's not the sex that gets you; it's the way they crumble when they're apart.

Antonio Banderas and Catherine Zeta-Jones: The Mask of Zorro/The Legend of Zorro

By and large Hollywood hasn't known what to do with these two lookers; it's as if each is too big a distraction for the average movie. Together, at least in these japes, the screen practically crackles.

Holly Hunter and Harvey Keitel: The Piano

Who knows why Holly and Harve haven't got back together after all these years: what he makes of a hole in her stocking is the stuff that dreams are made of.

Tony Leung and Maggie Cheung: In the Mood for Love

A dress rehearsal for a love affair between two spurned partners; the sex is all in their eyes.

Tom Charity
tom.charity@lovefilm.com